Self-assembly of ten molecules into nanometre-sized organic host frameworks

M Fujita, D Oguro, M Miyazawa, H Oka, K Yamaguchi… - Nature, 1995 - nature.com
THE synthesis of hollow, nanometrescale molecular "container compounds 1,2 makes possible
the creation of localized chemical microenvironments with properties different from those …

New Cucurbituril Homologues:  Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril (n = 5, 7, and 8)

…, JK Kang, S Sakamoto, K Yamaguchi… - Journal of the …, 2000 - ACS Publications
Cucurbituril (CB [6]) is a hexameric macropolycyclic compound self-assembled from an acid-catalyzed
condensation reaction of glycoluril and formaldehyde. 1, 2 Its easy synthesis and …

Spontaneous assembly of ten components into two interlocked, identical coordination cages

M Fujita, N Fujita, K Ogura, K Yamaguchi - Nature, 1999 - nature.com
Supermolecules consisting of interlinked ring-like molecules (catenanes) 1 are an interesting
target for chemical synthesis both for their intrinsic interest as non-covalently bound but …

Self-Assembled M24L48 Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation

…, Y Ishido, S Sato, T Ozeki, Y Sei, K Yamaguchi… - Science, 2010 - science.org
Self-assembly is a powerful technique for the bottom-up construction of discrete, well-defined
nanoscale structures. Large multicomponent systems (with more than 50 components) …

Selective inclusion of a hetero‐guest pair in a molecular host: formation of stable charge‐transfer complexes in cucurbit [8] uril

…, E Lee, J Kim, S Sakamoto, K Yamaguchi… - Angewandte …, 2001 - Wiley Online Library
Angew. Chem. 2001, 113, Nr. 8 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001 0044-8249/01/11308-1575
$17.50+. 50/0 1575 spectrometry. The chemical shifts of the …

Rewritable phosphorescent paper by the control of competing kinetic and thermodynamic self-assembling events

A Kishimura, T Yamashita, K Yamaguchi, T Aida - Nature Materials, 2005 - nature.com
Security inks have become of increasing importance 1 , 2 . They are composed of invisible
substances that provide printed images that are not able to be photocopied, and are readable …

Cucurbit[n]uril Derivatives Soluble in Water and Organic Solvents

…, JW Lee, S Sakamoto, K Yamaguchi… - Angewandte …, 2001 - Wiley Online Library
Cucurbituril (CB [6]), a macrocyclic cavitand comprising six glycoluril units, has a cavity of
$5.5 diameter that is accessible through two identical carbonyl-fringed portals.[1] Similar to …

A nanometre-sized hexahedral coordination capsule assembled from 24 components

N Takeda, K Umemoto, K Yamaguchi, M Fujita - Nature, 1999 - nature.com
Molecular capsules consist of closed, hollow frameworks within which encapsulated molecules
are isolated from interaction with external molecules 1 . In this environment, otherwise …

Finite, spherical coordination networks that self-organize from 36 small components

…, T Ozeki, S Sakamoto, K Yamaguchi… - Angewandte Chemie …, 2004 - pfwww.kek.jp
Highly symmetric structures often appear in nature as revealed by, for example, the capsids
of spherical viruses that possess icosahedral symmetry consisting of 60n identical protein …

Novel molecular drug carrier: encapsulation of oxaliplatin in cucurbit [7] uril and its effects on stability and reactivity of the drug

…, SY Kim, YH Ko, S Sakamoto, K Yamaguchi… - Organic & …, 2005 - pubs.rsc.org
Oxaliplatin forms a stable 1 : 1 inclusion complex with cucurbit[7]uril as indicated by NMR,
mass spectrometry, isothermal titration calorimetry and X-ray crystallography. The …